Oh yes; anyone who has seen Archer and Kimblee interact knows they're very close - it could easily be assumed that Archer would at least know about Kimblee's involvement in Team Rocket, if not actually be a member of the organization himself!

And if she taunted TR like that oh man would Archer go after her with the anonymous texts. Because EVERYTHING YOU CAN DO HE CAN DO SO MUCH BETTER TOTALLY!!!!!

I am so looking forward to anything involving these too, oh my god. 8D